| Tobey Maguire | Spider-Man / Peter Parker |
| Willem Dafoe | Green Goblin / Norman Osborn |
| Kirsten Dunst | Mary Jane Watson |
| James Franco | Harry Osborn |
| Cliff Robertson | Ben Parker |
| Rosemary Harris | May Parker |
| J.K. Simmons | J. Jonah Jameson |
| Joe Manganiello | Flash Thompson |
| Gerry Becker | Maximilian Fargas |
| Bill Nunn | Joseph 'Robbie' Robertson |
| Director | Sam Raimi |
| Producer | Avi Arad; Ian Bryce; Laura Ziskin |
| Writer | Stan Lee; Steve Ditko; David Koepp |
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| Disc 1: | Disc 1 "Weaving The Web:" Subtitled Factoids (Pop On Production Notes and Historical Facts) Commentary: Sam Raimi (Director), Kirsten Dunst, Laura Ziskin (Producer) & Grant Curtis (Co-Producer) SFX Commentary: John Dykstra (Special Effects Designer) & Visual Effects Crew Branching Web-i-sodes Music Videos: Chad Kroeger featuring Josey Scott: Hero, Sum 41: What We're All About TV Spots Theatrical Trailers Filmographies & Character Files DVD-ROM Features: · Comic/Feature Comparison · Record Your Own Commentary · Countdown To Spider-Man 2 · Weblinks |
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| Disc 2: | Disc 2 HBO Making of Spider-Man Spider-Mania: AN E! Entertainment Special Director Profile: Sam Rami Composer Profile: Danny Elfman Screen Tests: Tobey Maguire, J.K. Simmons & CGI Spider-Man Costume and Makeup Tests Gag/Outtake Reel Conceptual Art & Production Design Gallery Historical Documentary: Spider-Man: The Mythology of the 21st Century The Spider-Man Comic Archives Rogues Gallery The Loves of Peter Parker Comic Book Artist Gallery Activision Game: Hints and Tips DVD-ROM Features: · Activision PC Game, 2 Playable Levels · 3 Exclusive Marvel dot.comics: · Spider-Man: Blue #1 · Black Cat #1 · Peter Parker: Return of the Goblin Spider-Man Visualizer |